Mathematics
Q&A for people studying math at any level and professionals in related fields
Area 51
Stack Exchange Network staging zone, where users come together to build new Q&A sites
Ask Different
Q&A for power users of Apple hardware and software
Cross Validated
Q&A for statisticians, data analysts, data miners and data visualization experts
Meta Stack Overflow
Q&A for meta-discussion of the Stack Exchange family of Q&A websites
English Language & Usage
Q&A for linguists, etymologists, and serious English language enthusiasts
User Experience
Q&A for user experience researchers and experts
Theoretical Computer Science
Q&A for theoretical computer scientists and researchers in related fields
Unix & Linux
Q&A for users of Linux, FreeBSD and other Un*x-like operating systems.
Server Fault
Q&A for professional system and network administrators
Programmers
Q&A for professional programmers interested in conceptual questions about software development
TeX - LaTeX
Q&A for users of TeX, LaTeX, ConTeXt, and related typesetting systems
Computational Science
Q&A for scientists using computers to solve scientific problems
Writers
Q&A for authors, editors, reviewers, professional writers, and aspiring writers
Libraries & Information Science
Q&A for librarians and library professionals
Personal Productivity
Q&A for people wanting to improve their personal productivity
Board & Card Games
Q&A for people who like playing board games, designing board games or modifying the rules of existing board games